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Gasoline
Testing Program
A routine
gasoline or aviation gasoline sample will be analyzed for most or all of
the following parameters to meet specifications established in Nevada
Administrative Code Section 590 and, by reference, ASTM D4814-97b or
D910-97. ASTM methods may be obtained by phone, fax or email from either
the Reno or Las Vegas laboratories or by directly contacting ASTM
Technical Standards.
Vapor
Vapor Pressure by ASTM D5191 – Vapor Pressure is a physical measure of gasoline volatility. High vapor
pressures and a low distillation temperature for 10% evaporated both
help cold starting. Under hot-operating conditions, high vapor pressure
also contributes to vapor lock and increases vapor formation in fuel
tanks and carburetors. The amount of vapors formed in fuel tanks and
carburetors, which must be contained by evaporative loss control system,
are related to the vapor pressure and distillation temperatures. In
order to reduce overloading the vehicle's control systems, the
Environmental Protection Agency has placed maximum limits on gasoline's
vapor pressure during the ozone season (May 1 - September 15). Also, the
Washoe County Health Department has placed even lower vapor pressure
requirements for ozone non-attainment areas of Washoe County during the
period of June 1 - September 15. Hydrocarbon emissions are precursors to
the formation of ozone (smog).
To assure that fuels have the proper volatility characteristics,
refineries adjust gasoline seasonally. During the cold, winter months,
fuel will be more volatile. This helps good "cold" start and
warm-up performance. During the hot summer months, the fuel tends to be
less volatile. This will help to minimize the incidence of vapor lock
and hot driveability problems.
Since there are six seasonal classes of gasoline, only a sufficient
quantity of fuel that can be consumed in a short period of time should
be sold to a consumer/user.
The
Environmental Protection Agency regulations allow 1.0 psi higher vapor
pressure for gasoline-ethanol blends containing 9 to 10 volume %
ethanol. The exception is that the Nevada Department of Agriculture has placed even lower vapor pressure requirements for ozone
non-attainment areas of Clark County during the period of October 1 –
March 31.
Distillation
Distillation by ASTM D3710 or ASTM D86 –The
"distillation" standard is one of several tests used to
address gasoline's vaporization characteristics. Gasoline is metered in
liquid form, through the fuel injectors (or carburetor), and mixed with
air and atomized before entering the cylinders. Therefore, it is very
important that a fuel's tendency to evaporate is controlled to certain
standards. A fuel's ability to vaporize or change from liquid to vapor
is referred to as its volatility. In gasoline, the distillation
characteristics, along with vapor pressure, define and control starting,
warm-up, acceleration, vapor lock, crankcase oil dilution, and, in part,
fuel economy and carburetion icing.
The tendency of a fuel to vaporize is also characterized by determining
a series of temperatures at which various percentages of the fuel have
evaporated (boiling temperatures), as described in ASTM D86, Test Method
for Distillation of Petroleum Products. The temperatures at which 10%,
50%, and 90% evaporation occurs are often used to characterize the
volatility of gasoline.
The 10% evaporated temperature is directly affected by the seasonal
blending of the gasoline. This temperature must be low enough to provide
easy cold starting, but high enough to minimize the vapor lock and hot
weather driveability problems. Most cool weather driveability problems
occur from the use of summer season gasoline in the winter months. This
is especially true in premium grades, which normally have a high 10%
evaporated temperature.
The 50% evaporated temperature must be low enough to provide good
warm-up and cool weather driveability without being so low as to
contribute to hot driveability and vapor locking problems. This portion
of the gasoline greatly affects fuel economy on short trips.
The 90% and end-point evaporation temperatures must be low enough to
minimize crankcase and combustion chamber deposits, as well as spark
plug fouling and the dilution of engine oil.
If the end-point temperature exceeds the ASTM maximum requirement, it is
usually because of the presence of a distillate fuel such as No. 2
diesel. This contamination can be directly attributable to the delivery
of diesel prior to the delivery of the gasoline. This problem is avoided
if care is taken in handling the product.
Sulfur
Sulfur by ASTM D5623 – Sulfur
is an element that is normally found in varying amounts in all petroleum
products. As a result of combustion, sulfur compounds of an acidic or
corrosive nature are produced and contribute to combustion chamber and
valve deposits, exceptional wear on the engine, and increased atmosphere
pollution. Through recent EPA regulations, the sulfur limit for
on-highway diesel fuels has been reduced from 0.50% to 0.05% by weight.
High sulfur fuels are still available. However, they are not for highway
use and must be colored red. Also, the Internal Revenue Service requires
certain fuels to be dyed for tax purposes. Therefore, highway diesel
should not contain any dyes.
Oxygenates
Oxygenates by ASTM D4815 or D5845 –
oxygenates are compounds added to gasoline to provide more oxygen in the
combustion process, thus decreasing the amount of carbon monoxide
emitted from the vehicle. This
is usually ethanol and is used to meet wintertime oxygenate requirements
in Washoe and Clark Counties.
Octane
Octane screen by Near Infrared Spectroscopy –
Gasolines are most commonly
rated based on their Antiknock Index (AKI), a measure of octane quality.
The octane is a measure of gasoline's ability to resist knock or
auto-ignition. The fuel-air mixture in the cylinder of a spark ignition
engine will, under certain conditions, auto-ignite. This pre-firing may
cause an audible "ping" or knock and may also cause an engine
to continue running when turned off. Loss of power and damage to an
engine can occur when knocking is severe and prolonged.
The AKI of a motor fuel is the average of the Research Octane Number
(RON) and Motor Octane Number (MON) or (R+M)/2. This is also the number
displayed on the black and yellow octane decal posted on the gasoline
pump. Optimum performance and fuel economy is achieved when the AKI is
adequate for the engine in which it is combusted. There is no advantage
in using gasoline with a higher AKI than the engine requires to operate
knock-free.
Improper
octane fuel can lead to an increase in emissions of pollutants. Any
fuels found in non-compliance have confirmatory analysis performed by an
outside laboratory per ASTM D2699 and D2700.
Water/sediment
Water/sediment by Visual Inspection – Water and sediment in fuel is our program's most frequent consumer
complaint. As most are aware, water makes a very undesirable fuel and
sediment has a tendency to clog filters, carburetors and injectors. ASTM
requires gasoline to be visually free of undissolved water, sediment,
and suspended matter: it shall be clear and bright at ambient
temperatures or 70 F, whichever is higher. The presence of water
and/or sediment can lead to improper motor operation and thus excess
emissions of pollutants.
NOTE:
The reproducibility of each method
is applied before enforcement
action is taken. |